[(Pyrrolidin-1-yl)carbothioylsulfanyl]methyl pyrrolidine-1-carbodithioate
نویسندگان
چکیده
منابع مشابه
[(Pyrrolidin-1-yl)carbothioylsulfanyl]methyl pyrrolidine-1-carbodithioate
The title compound, C(11)H(18)N(2)S(4), was unexpectedly obtained during studies on the reactivity of the complex tris-(acac-κ(2)O,O')gallium(III) (acac is acetyl-acetonate) with C(4)H(8)NCS(2)H in dichloro-methane. The title compound shows disordered two pyrrolidine rings with major and minor occupancies of 0.546 (4) and 0.454 (4). Two (pyrrolidin-1-yl)carbothio-ylsulfanyl units are linked tog...
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The complete mol-ecule of the title diproline ester quinone, C(18)H(22)N(2)O(6), is generated by a crystallographic twofold axis, which passes through the centre of the benzene ring. Both -CO(2)Me groups are orientated to the same side of the benzene ring, with the carbonyl groups pointing roughly towards each other. The conformation of the proline residue is an envelope. In the crystal, a thre...
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The asymmetric unit of the title compound, [Sb(C(6)H(5))(3)Cl(2)]·C(10)H(16)N(2)S(4), comprises a bis-(pyrrolidinylthio-carbamo-yl) mol-ecule and a dichloro-triphenyl-anti-mony(V) complex. In the Sb complex, the central atom is coordinated by three C atoms of the three phenyl ligands and two Cl atoms in a slightly distorted trigonal-bipyramidal geometry. The thio-carbamoyl units, connected via ...
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In the title compound, C(12)H(14)N(2)OS, the pyrrolidine ring adopts an envelope conformation with the C atom at the 3-position as the flap and makes a dihedral angle of 65.80 (9)° with the benzene ring. In the crystal, N-H⋯O hydrogen bonds join c-glide related mol-ecules into chains extended along [001] that are further connected into (100) layers via C-H⋯O inter-actions.
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In the mol-ecular structure of title compound, C(18)H(13)NO(2), the succinimide ring is orientated away from the plane of the anthracene moiety by 71.94 (4)°. The crystal structure features three different types of inter-molecular inter-actions, viz. C-H⋯O, C-H⋯π and π-π bonds. Mol-ecules along the b axis stack on each other as a result of π-π inter-actions which have a centroid-centroid distan...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2010
ISSN: 1600-5368
DOI: 10.1107/s1600536810046027